食品中铝的分析方法改进及在风险监测中的应用
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广东省科技计划项目(20090320)


Improving the method for detecting aluminum in food and its application in risk monitoring
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    摘要:

    目的对测定食品中铝的国标分析方法进行改进、整合,为研制新的食品安全标准方法提供依据。开展广东各地面制食品中铝含量调查,为评估我省居民膳食暴露量及规范含铝添加剂使用提供依据。方法对GB/T 5009.182—2003中的消解和显色体系进行改进,用于监测添加含铝膨松剂的面制食品,同时采用GB/T 23374—2009和石墨炉原子吸收法测定各类食品中铝的本底值。结果 2006—2010年在全省城乡各地的超级市场、副食品商店、个体零售店采集各种面制食品2 369份。检测结果表明油条、油饼等油炸食品,馒头、包子等蒸制食品以及面包等烘烤食品中铝含量中位值分别为321.0、201.0和26.2 mg/kg,对照GB 2760—2011,以上3种面制食品中铝含量合格率分别为18.5%、31.6%和95.2%。结论建议将GB/T 5009.182—2003和GB/T 23374—2009合并,增加石墨炉原子吸收法,研制新的《食品中铝的测定》食品安全国家标准。连续5年的监测表明,广东省油炸和蒸制面制食品中铝超标问题较为普遍,FAO/WHO 2006年提出铝的每周耐受摄入量(PTWI)为1 mg/kg BW,按此评估,广东省居民食用面制食品摄入铝对健康可能造成危害的问题应引起关注。

    Abstract:

    Objective To integrate and improve the method for the determination of aluminum in food in order to provide data base for establishing a new National Food Safety Standard.To carry out an investigation on the aluminum content in flour products in Guangdong province to provide data base for evaluating human exposure to aluminum through diet and to standardize the use of aluminum-containing food additives.Methods Improved the digestion system and chromogenic system in the method of GB/T 5009.182—2003 and applied to detect the content of aluminum in wheaten food in which aluminum-containing food additives had been added as a leavening agent;and the background values of aluminum in food was detected by GB/T 23374—2009 and graphite furnace atomic absorption spectrometry.Results A total of 2 369 varied wheaten food samples were collected from supermarkets,grocery stores or kiosks located in different cities and villages in Guangdong province from 2006 to 2010.The results showed that the average contents of aluminum in deep-fried products like dough sticks and deep-fried cakes,steamed products like steamed stuffed bun and steamed bread,and bakery products like bakery bread were 321.0,201.0 and 26.2 mg/kg respectively,the eligibility for GB 2760—2011 in these three kinds of food listed above were 18.5%,31.6% and 95.2% respectively.Conclusion It is proposed to modify the GB/T 5009.182—2003 by adding graphite furnace atomic absorption spectrometry and integrating the GB/T 5009.182—2003 with GB/T 23374—2009 to establish a new National Food Safety Standard.The surveyed data continuously collected in the past 5 years indicated that aluminum-containing food additives had been widely used in deep-fried and steamed wheaten food and lead to a prevalence of exceeding the standard limit value of aluminum.FAO/WHO propounded in the year 2006 that the(provisional tolerable weekly intake) PTWI was 1 mg/kg BW.According to this guidance value,more attention should be paid to the problem of aluminum contamination through the ingestion of wheaten food,which might do harm to the health of residents in Guangdong province.

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梁春穗,胡曙光,王晶,李海.食品中铝的分析方法改进及在风险监测中的应用[J].中国食品卫生杂志,2012,24(2):97-101.

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